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Links New Chemistry A transition metal borylene
complex
stabilized by a non- carbonyl
ligand set: formation by
spontaneous halide loss to give an
extremely short metal- -boron
bond (video). (work by David Addy) |
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References Listed
below is a selection of published papers from 2007 and earlier (see ‘further links’ for other years and S.
Aldridge CV – under ‘group members’ – for full publication list). Click on
the relevant citations for links to the electronic versions of the article. Cationic
Terminal Aminoborylene Complexes: Controlled
Stepwise Insertion into M=B and B=N Double Bonds. G.A. Pierce, S.
Aldridge, C. Jones, T. Gans-Eichler, A. Stasch, N.D. Coombs and D.J. Willock. Angew. Chem., Int. Ed., 2007, 46,
2043-2046 (selected as a VIP paper). Cationic
terminal borylene complexes: inter-conversion of
amino- and alkoxy-borylenes via an
unprecedented Meerwein-Ponndorf hydride transfer. D.L. Kays (née
Coombs), J.K. Day, S. Aldridge, R.W. Harrington and W. Clegg. Angew. Chem., Int. Ed., 2006,
45, 3513-3516. Cationic
terminal borylene complexes: structure/bonding
analysis and [4+1] cycloaddition reactivity of a BN
vinylidene analogue. S. Aldridge, C. Jones, T. Gans-Eichler, A. Stasch, D.L. Kays (née Coombs), N.D. Coombs and D.J. Willock. Angew. Chem., Int. Ed., 2006,
45, 6118-6122. Selective electrochemical detection of
hydrogen fluoride by ambiphilic ferrocene
derivatives. C. Bresner, S. Aldridge, I.A. Fallis,
C.Jones and L.-L. Ooi. Angew. Chem. Int. Ed., 2005,
44, 3606-3609. Cationic
terminal borylene complexes: a B/N vinylidene analogue and M=B metathesis chemistry. D.L. Kays (née
Coombs), S. Aldridge, J.K. Day and L.-L. Ooi. Angew. Chem. Int. Ed., 2005, 44,
7457-7460. This paper was featured as a highlight in Science, 2005, 310, 747. Cationic terminal borylenes by halide abstraction: synthesis, spectroscopic
and structural characterization of an Fe=B double
bond. D.L. Coombs, S.
Aldridge, C. Jones and D.J. Willock. J. Am. Chem. Soc., 2003,
125, 6356-6357. This paper was featured as a highlight in Chemistry
and Industry, 2003, issue 12, 26-27. |
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Further Information References Further Links 2007 and earlier |
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