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0 copy.jpg

 

 

     New Chemistry

 

 

 

     A transition metal borylene

     complex stabilized by a non-

     carbonyl ligand set: formation

     by spontaneous halide loss to

     give an extremely short metal-

     -boron bond (video).

     (work by David Addy)

 

 

 

 

Aldridge


References

 

Listed below is a selection of published papers from 2007 and earlier (see ‘further links’ for other years and S. Aldridge CV – under ‘group members’ – for full publication list). Click on the relevant citations for links to the electronic versions of the article.

 

Cationic Terminal Aminoborylene Complexes: Controlled Stepwise Insertion into M=B and B=N Double Bonds.

G.A. Pierce, S. Aldridge, C. Jones, T. Gans-Eichler, A. Stasch, N.D. Coombs and D.J. Willock.

Angew. Chem., Int. Ed., 2007, 46, 2043-2046 (selected as a VIP paper).

 

Cationic terminal borylene complexes: inter-conversion of amino- and alkoxy-borylenes via an unprecedented Meerwein-Ponndorf hydride transfer.

D.L. Kays (née Coombs), J.K. Day, S. Aldridge, R.W. Harrington and W. Clegg.

Angew. Chem., Int. Ed., 2006, 45, 3513-3516.

 

Cationic terminal borylene complexes: structure/bonding analysis and [4+1] cycloaddition reactivity of a BN vinylidene analogue.

S. Aldridge, C. Jones, T. Gans-Eichler, A. Stasch, D.L. Kays (née Coombs), N.D. Coombs and D.J. Willock.

Angew. Chem., Int. Ed., 2006, 45, 6118-6122.

 

Selective electrochemical detection of hydrogen fluoride by ambiphilic ferrocene derivatives.

C. Bresner, S. Aldridge, I.A. Fallis, C.Jones and L.-L. Ooi.

Angew. Chem. Int. Ed., 2005, 44, 3606-3609.

 

Cationic terminal borylene complexes: a B/N vinylidene analogue and M=B metathesis chemistry.

D.L. Kays (née Coombs), S. Aldridge, J.K. Day and L.-L. Ooi.

Angew. Chem. Int. Ed., 2005, 44, 7457-7460.

This paper was featured as a highlight in Science, 2005, 310, 747.

 

Cationic terminal borylenes by halide abstraction: synthesis, spectroscopic and structural characterization of an Fe=B double bond.

D.L. Coombs, S. Aldridge, C. Jones and D.J. Willock.

J. Am. Chem. Soc., 2003, 125, 6356-6357.

This paper was featured as a highlight in Chemistry and Industry, 2003, issue 12, 26-27.

 


 

 

 

 

 

     Further Information

 

 

 

     Research Areas Overview

         Multiply bonded systems

         Metal boryl complexes

         Sensors

         Sterically demanding ligands

         References

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         Current project funding

 

 

 

 

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