A transition metal borylene
complex stabilized by a non-
carbonyl ligand set: formation
by spontaneous halide loss to
give an extremely short metal-
-boron bond (video).
(work by David Addy)
Listed below is a selection of published and in press articles from 2011 (see ‘further links’ for other years and S. Aldridge CV – under ‘group members’ – for full publication list). Click on the relevant citation for the link to the electronic version of the article.
Iridium-mediated borylation of benzylic C-H bonds by borohydride.
C.Y. Tang, W. Smith, A.L. Thompson, D. Vidovic, S. Aldridge.
This paper was selected by the editors of Angew. Chem., Int. Ed. as a ‘hot article’.
Responses to unsaturation in iridium mono(N-heterocyclic carbene) complexes: oligomerization of [LIr(H)2Cl] and [LIr(H)2]+
C.Y.Tang, J. Lednik, A.L. Thompson, S. Aldridge.
Group 3 and lanthanide boryl compounds: syntheses, structures and bonding analysis of Sc–B, Y–B and Lu–B s-coordinated NHC analogues.
L.M.A. Saleh, K. Hassomal, A.V. Protchenko, A.D. Schwarz, S. Aldridge, C. Jones, N. Kaltsoyannis, P. Mountford.
Tuning Main Group redox chemistry through steric loading: subvalent Group 13 metal complexes of carbazolyl ligands.
H.B. Mansaray, M. Kelly, D. Vidovic, S. Aldridge.
Probing the intrinisic structure and dynamics of aminoborane coordination at late transition metal centers: k1-binding in [CpRu(PR3)2(H2BNCy2)]+.
D. Vidovic, D.A. Addy, T. Krämer, J. McGrady, S. Aldridge.
Borane to boryl hydride to borylene dihydride: explicit demonstration of boron-to-metal a-hydride migration in aminoborane activation.
M. O’Neill, D.A. Addy, I. Riddlestone, M. Kelly, N. Phillips, S. Aldridge
Extending the chain: synthetic, structural and reaction chemistry of a BN allenylidene analogue.
J. Niemeyer, D.A. Addy, A.L. Thompson, M. Kelly, S. Aldridge.
2011 and in press